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41.
《Journal of separation science》2017,40(7):1482-1492
We developed a straightforward, robust, and relatively fast method for the analysis of amino acids by mixed‐mode high‐performance liquid chromatography coupled to electrospray ionization tandem mass spectrometry. The method does not involve derivatization and allows the detection of 21 amino acids, representing a wide range of isoelectric points, in less than 40 min. Chromatographic separation was governed by a silica‐based mixed‐mode column providing simultaneous hydrophobic and ion exchange separation mechanisms. The use of tandem mass spectrometry increased selectivity, reducing potential problems associated with poor selectivity in the chromatographic system. For an injection volume of 1 μL, we obtained detection limits <3 μM for the majority of analytes. For all analytes, a linearity of r > 0.99 was obtained, recovery in matrix was >86%, and the retention times were highly reproducible. The method was successfully applied to soil solution and fungal culture samples, demonstrating the advantages in successfully avoiding issues associated with high amounts of substances that may interfere with derivatization‐based methods. This method represents an alternative to derivatization‐based methods and can be applied in areas where sample matrices are highly complex. 相似文献
42.
《Macromolecular bioscience》2017,17(7)
d ‐Fructose modified poly(ε‐caprolactone)‐polyethylene glycol (PCL‐PEG‐Fru) diblock amphiphile is synthesized via Cu(I)‐catalyzed click chemistry, which self‐assembles with D‐α‐tocopheryl polyethylene glycol 1000 succinate (TPGS) into PCL‐PEG‐Fru/TPGS mixed micelles (PPF MM). It has been proven that glucose transporter (GLUT)5 is overexpressed in MCF‐7 cells other than L929 cells. In this study, PPF MM exhibit a significantly higher uptake efficiency than fructose‐free PCL‐PEG‐N3/TPGS mixed micelles in both 2D MCF‐7 cells and 3D tumor spheroids. Also, the presence of free d ‐fructose competitively inhibits the internalization of PPF MM in MCF‐7 cells other than L929 cells. PPF MM show selective tumor accumulation in MCF‐7 breast tumor bearing mice xenografts. Taken together, PPF MM represent a promising nanoscale carrier system to achieve GLUT5‐mediated cell specific delivery in cancer therapy.
43.
In this paper, we propose a new hierarchical Archimedean copula construction based on multivariate compound distributions. This new imbrication technique is derived via the construction of a multivariate exponential mixture distribution through compounding. The absence of nesting and marginal conditions, contrarily to the nested Archimedean copulas approach, leads to major advantages, such as a flexible range of possible combinations in the choice of distributions, the existence of explicit formulas for the distribution of the sum, and computational ease in high dimensions. A balance between flexibility and parsimony is targeted. After presenting the construction technique, properties of the proposed copulas are investigated and illustrative examples are given. A detailed comparison with other construction methodologies of hierarchical Archimedean copulas is provided. Risk aggregation under this newly proposed dependence structure is also examined. 相似文献
44.
Sturmian comparison theory for half‐linear and nonlinear differential equations via Picone identity 下载免费PDF全文
Abdullah Özbekler 《Mathematical Methods in the Applied Sciences》2017,40(8):3100-3110
In this paper, Sturmian comparison theory is developed for the pair of second‐order differential equations; first of which is the nonlinear differential equations of the form (1) and the second is the half‐linear differential equations (2) where Φα (s ) = |s |α ? 1s and α 1 > ? > α m > β > α m + 1 > ? > α n > 0. Under the assumption that the solution of 2 has two consecutive zeros, we obtain Sturm–Picone type and Leighton type comparison theorems for 1 by employing the new nonlinear version of Picone formula that we derive. Wirtinger type inequalities and several oscillation criteria are also attained for 1 . Examples are given to illustrate the relevance of the results. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
45.
On the mixed problem for the semilinear Darcy‐Forchheimer‐Brinkman PDE system in Besov spaces on creased Lipschitz domains 下载免费PDF全文
Robert Gutt Mirela Kohr Sergey E. Mikhailov Wolfgang L. Wendland 《Mathematical Methods in the Applied Sciences》2017,40(18):7780-7829
The purpose of this paper is to study the mixed Dirichlet‐Neumann boundary value problem for the semilinear Darcy‐Forchheimer‐Brinkman system in L p ‐based Besov spaces on a bounded Lipschitz domain in , with p in a neighborhood of 2. This system is obtained by adding the semilinear term | u | u to the linear Brinkman equation. First, we provide some results about equivalence between the Gagliardo and nontangential traces, as well as between the weak canonical conormal derivatives and the nontangential conormal derivatives. Various mapping and invertibility properties of some integral operators of potential theory for the linear Brinkman system, and well‐posedness results for the Dirichlet and Neumann problems in L p ‐based Besov spaces on bounded Lipschitz domains in (n ≥3) are also presented. Then, using integral potential operators, we show the well‐posedness in L 2‐based Sobolev spaces for the mixed problem of Dirichlet‐Neumann type for the linear Brinkman system on a bounded Lipschitz domain in (n ≥3). Further, by using some stability results of Fredholm and invertibility properties and exploring invertibility of the associated Neumann‐to‐Dirichlet operator, we extend the well‐posedness property to some L p ‐based Sobolev spaces. Next, we use the well‐posedness result in the linear case combined with a fixed point theorem to show the existence and uniqueness for a mixed boundary value problem of Dirichlet and Neumann type for the semilinear Darcy‐Forchheimer‐Brinkman system in L p ‐based Besov spaces, with p ∈(2?ε ,2+ε ) and some parameter ε >0. 相似文献
46.
M. Ferreira M. M. Rodrigues N. Vieira 《Mathematical Methods in the Applied Sciences》2017,40(18):7033-7050
In this work, we obtain the fundamental solution (FS) of the multidimensional time‐fractional telegraph Dirac operator where the 2 time‐fractional derivatives of orders α∈]0,1] and β∈]1,2] are in the Caputo sense. Explicit integral and series representation of the FS are obtained for any dimension. We present and discuss some plots of the FS for some particular values of the dimension and of the fractional parameters α and β. Finally, using the FS, we study some Poisson and Cauchy problems. 相似文献
47.
48.
Muhammad Saad Khan Cornelius Borecho Bavoh Khor Siak Foo Azmi Mohd Shariff Zamzila Kassim Nurzatil Aqmar Bt Othman Bhajan Lal Iqbal Ahmed Mohammad Azizur Rahman Sina Rezaei Gomari 《Molecules (Basel, Switzerland)》2021,26(2)
This study evaluates the kinetic hydrate inhibition (KHI) performance of four quaternary ammonium hydroxides (QAH) on mixed CH4 + CO2 hydrate systems. The studied QAHs are; tetraethylammonium hydroxide (TEAOH), tetrabutylammonium hydroxide (TBAOH), tetramethylammonium hydroxide (TMAOH), and tetrapropylammonium hydroxide (TPrAOH). The test was performed in a high-pressure hydrate reactor at temperatures of 274.0 K and 277.0 K, and a concentration of 1 wt.% using the isochoric cooling method. The kinetics results suggest that all the QAHs potentially delayed mixed CH4 + CO2 hydrates formation due to their steric hindrance abilities. The presence of QAHs reduced hydrate formation risk than the conventional hydrate inhibitor, PVP, at higher subcooling conditions. The findings indicate that increasing QAHs alkyl chain lengths increase their kinetic hydrate inhibition efficacies due to better surface adsorption abilities. QAHs with longer chain lengths have lesser amounts of solute particles to prevent hydrate formation. The outcomes of this study contribute significantly to current efforts to control gas hydrate formation in offshore petroleum pipelines. 相似文献
49.
Matteo Velenosi Pasquale Crupi Rocco Perniola Antonio Domenico Marsico Antonella Salerno Herv Alexandre Nicoletta Archidiacono Mario Ventura Maria Francesca Cardone 《Molecules (Basel, Switzerland)》2021,26(4)
Mixed fermentation using Starmerella bacillaris and Saccharomyces cerevisiae has gained attention in recent years due to their ability to modulate the qualitative parameters of enological interest, such as the color intensity and stability of wine. In this study, three of the most important red Apulian varieties were fermented through two pure inoculations of Saccharomyces cerevisiae strains or the sequential inoculation of Saccharomyces cerevisiae after 48 h from Starmerella bacillaris. The evolution of anthocyanin profiles and chromatic characteristics were determined in the produced wines at draining off and after 18 months of bottle aging in order to assess the impact of the different fermentation protocols on the potential color stabilization and shelf-life. The chemical composition analysis showed titratable acidity and ethanol content exhibiting marked differences among wines after fermentation and aging. The 48 h inoculation delay produced wines with higher values of color intensity and color stability. This was ascribed to the increased presence of compounds, such as stable A-type vitisins and reddish/violet ethylidene-bridge flavonol-anthocyanin adducts, in the mixed fermentation. Our results proved that the sequential fermentation of Starmerella bacillaris and Saccharomyces cerevisiae could enhance the chromatic profile as well as the stability of the red wines, thus improving their organoleptic quality. 相似文献
50.
This paper is devoted to studying maximal singular integrals and Marcinkiewicz integrals with rough kernels in a mixed homogeneity setting. Assuming that the kernels satisfy certain rather weak size conditions, the boundedness of such operators on the mixed radial-angular spaces are established, respectively. Meanwhile, the corresponding vector-valued versions are also given. 相似文献